Theory of cyclic voltammetry in tubular electrodes under no flow conditions

M Thompson; J Davis; RG Compton

doi:10.1016/j.jelechem.2005.10.014

Theory of cyclic voltammetry in tubular electrodes under no flow conditions

M Thompson
, J Davis
, RG Compton

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Numerical modelling of the concentration profile of the electroactive species within a tubular electrode under diffusion only conditions is used to simulate cyclic voltammetry experiments. Nernst conditions are assumed at the electrode surface. The simulated peak current is compared to that given by the Randles-(S) over tilde ev (e) over tilde ik formula in order to determine the conditions of electrode size and voltage sweep rate under which there is no significant deviation from the Randles-(S) over tilde ev (e) over tilde ik result. (c) 2005 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	56-59
Journal	Journal of Electroanalytical Chemistry
Volume	587
Issue number	1
DOIs	https://doi.org/10.1016/j.jelechem.2005.10.014
Publication status	Published (in print/issue) - Feb 2006

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10.1016/j.jelechem.2005.10.014

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title = "Theory of cyclic voltammetry in tubular electrodes under no flow conditions",

abstract = "Numerical modelling of the concentration profile of the electroactive species within a tubular electrode under diffusion only conditions is used to simulate cyclic voltammetry experiments. Nernst conditions are assumed at the electrode surface. The simulated peak current is compared to that given by the Randles-(S) over tilde ev (e) over tilde ik formula in order to determine the conditions of electrode size and voltage sweep rate under which there is no significant deviation from the Randles-(S) over tilde ev (e) over tilde ik result. (c) 2005 Elsevier B.V. All rights reserved.",

author = "M Thompson and J Davis and RG Compton",

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AU - Thompson, M

AU - Davis, J

AU - Compton, RG

PY - 2006/2

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N2 - Numerical modelling of the concentration profile of the electroactive species within a tubular electrode under diffusion only conditions is used to simulate cyclic voltammetry experiments. Nernst conditions are assumed at the electrode surface. The simulated peak current is compared to that given by the Randles-(S) over tilde ev (e) over tilde ik formula in order to determine the conditions of electrode size and voltage sweep rate under which there is no significant deviation from the Randles-(S) over tilde ev (e) over tilde ik result. (c) 2005 Elsevier B.V. All rights reserved.

AB - Numerical modelling of the concentration profile of the electroactive species within a tubular electrode under diffusion only conditions is used to simulate cyclic voltammetry experiments. Nernst conditions are assumed at the electrode surface. The simulated peak current is compared to that given by the Randles-(S) over tilde ev (e) over tilde ik formula in order to determine the conditions of electrode size and voltage sweep rate under which there is no significant deviation from the Randles-(S) over tilde ev (e) over tilde ik result. (c) 2005 Elsevier B.V. All rights reserved.

U2 - 10.1016/j.jelechem.2005.10.014

DO - 10.1016/j.jelechem.2005.10.014

M3 - Article

VL - 587

SP - 56

EP - 59

JO - Journal of Electroanalytical Chemistry

JF - Journal of Electroanalytical Chemistry

IS - 1

ER -

Theory of cyclic voltammetry in tubular electrodes under no flow conditions

Abstract

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