Theory of cyclic voltammetry in tubular electrodes under no flow conditions

M Thompson, J Davis, RG Compton

    Research output: Contribution to journalArticle

    4 Citations (Scopus)

    Abstract

    Numerical modelling of the concentration profile of the electroactive species within a tubular electrode under diffusion only conditions is used to simulate cyclic voltammetry experiments. Nernst conditions are assumed at the electrode surface. The simulated peak current is compared to that given by the Randles-(S) over tilde ev (e) over tilde ik formula in order to determine the conditions of electrode size and voltage sweep rate under which there is no significant deviation from the Randles-(S) over tilde ev (e) over tilde ik result. (c) 2005 Elsevier B.V. All rights reserved.
    LanguageEnglish
    Pages56-59
    JournalJournal of Electroanalytical Chemistry
    Volume587
    Issue number1
    DOIs
    Publication statusPublished - Feb 2006

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    Cyclic voltammetry
    Electrodes
    Electric potential
    Experiments

    Cite this

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    abstract = "Numerical modelling of the concentration profile of the electroactive species within a tubular electrode under diffusion only conditions is used to simulate cyclic voltammetry experiments. Nernst conditions are assumed at the electrode surface. The simulated peak current is compared to that given by the Randles-(S) over tilde ev (e) over tilde ik formula in order to determine the conditions of electrode size and voltage sweep rate under which there is no significant deviation from the Randles-(S) over tilde ev (e) over tilde ik result. (c) 2005 Elsevier B.V. All rights reserved.",
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    Theory of cyclic voltammetry in tubular electrodes under no flow conditions. / Thompson, M; Davis, J; Compton, RG.

    In: Journal of Electroanalytical Chemistry, Vol. 587, No. 1, 02.2006, p. 56-59.

    Research output: Contribution to journalArticle

    TY - JOUR

    T1 - Theory of cyclic voltammetry in tubular electrodes under no flow conditions

    AU - Thompson, M

    AU - Davis, J

    AU - Compton, RG

    PY - 2006/2

    Y1 - 2006/2

    N2 - Numerical modelling of the concentration profile of the electroactive species within a tubular electrode under diffusion only conditions is used to simulate cyclic voltammetry experiments. Nernst conditions are assumed at the electrode surface. The simulated peak current is compared to that given by the Randles-(S) over tilde ev (e) over tilde ik formula in order to determine the conditions of electrode size and voltage sweep rate under which there is no significant deviation from the Randles-(S) over tilde ev (e) over tilde ik result. (c) 2005 Elsevier B.V. All rights reserved.

    AB - Numerical modelling of the concentration profile of the electroactive species within a tubular electrode under diffusion only conditions is used to simulate cyclic voltammetry experiments. Nernst conditions are assumed at the electrode surface. The simulated peak current is compared to that given by the Randles-(S) over tilde ev (e) over tilde ik formula in order to determine the conditions of electrode size and voltage sweep rate under which there is no significant deviation from the Randles-(S) over tilde ev (e) over tilde ik result. (c) 2005 Elsevier B.V. All rights reserved.

    U2 - 10.1016/j.jelechem.2005.10.014

    DO - 10.1016/j.jelechem.2005.10.014

    M3 - Article

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    SP - 56

    EP - 59

    JO - Journal of Electroanalytical Chemistry

    T2 - Journal of Electroanalytical Chemistry

    JF - Journal of Electroanalytical Chemistry

    SN - 1572-6657

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