The application of CE-MS in the trace analysis of environmental pollutants and food contaminants

Virginia Rodriguez Robledo, Franklin Smyth

    Research output: Contribution to journalArticle

    38 Citations (Scopus)

    Abstract

    In this review, selected applications of CE-MS in recent years have been highlighted for the separation, detection and determination of environmental pollutants and food contaminants in selected samples. Trace analysis by CE-MS of analytes such as low molecular mass amines, nitroaromatics, alkylphosphonic acids, azo dyes, antidepressants, and antibiotic drugs, among others, in air, sediment and water samples have been reviewed. The CE-MS analysis of pesticides such as triazolopyrimidine sulphoanilides, different types of antibiotics (sulphonamides, beta-lactones, quinolones and tetracyclines) and other exogenous compounds such as acrylamide and toxic oligopeptides in food samples has also been reviewed. The review gives details on the fragmentations, where available, that the ionic species exhibit in-source and in ion trap, triple quadrupole and ToF MS analysers. A critical evaluation is also given of these recent CE-MS analytical methods for the separation, detection and determination of trace levels of such pollutants and contaminants with analytical information on the treatment of the samples, CE separation conditions, linearity ranges, LODs and recoveries from the different matrices presented.
    LanguageEnglish
    Pages1647-1660
    JournalElectrophoresis
    Volume30
    Issue number10, Sp
    DOIs
    Publication statusPublished - May 2009

    Fingerprint

    Trace analysis
    Environmental Pollutants
    Impurities
    Azo Compounds
    Anti-Bacterial Agents
    Tetracyclines
    Oligopeptides
    Acrylamide
    Poisons
    Quinolones
    Sulfonamides
    Molecular mass
    Lactones
    Pesticides
    Antidepressive Agents
    Amines
    Sediments
    Ions
    Recovery
    Acids

    Cite this

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    title = "The application of CE-MS in the trace analysis of environmental pollutants and food contaminants",
    abstract = "In this review, selected applications of CE-MS in recent years have been highlighted for the separation, detection and determination of environmental pollutants and food contaminants in selected samples. Trace analysis by CE-MS of analytes such as low molecular mass amines, nitroaromatics, alkylphosphonic acids, azo dyes, antidepressants, and antibiotic drugs, among others, in air, sediment and water samples have been reviewed. The CE-MS analysis of pesticides such as triazolopyrimidine sulphoanilides, different types of antibiotics (sulphonamides, beta-lactones, quinolones and tetracyclines) and other exogenous compounds such as acrylamide and toxic oligopeptides in food samples has also been reviewed. The review gives details on the fragmentations, where available, that the ionic species exhibit in-source and in ion trap, triple quadrupole and ToF MS analysers. A critical evaluation is also given of these recent CE-MS analytical methods for the separation, detection and determination of trace levels of such pollutants and contaminants with analytical information on the treatment of the samples, CE separation conditions, linearity ranges, LODs and recoveries from the different matrices presented.",
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    The application of CE-MS in the trace analysis of environmental pollutants and food contaminants. / Rodriguez Robledo, Virginia; Smyth, Franklin.

    In: Electrophoresis, Vol. 30, No. 10, Sp, 05.2009, p. 1647-1660.

    Research output: Contribution to journalArticle

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