Surface-to-Depth Analysis of Functionalized Multi-Wall Carbon Nanotubes (FMWCNTS)

TIT Okpalugo, P Papakonstantinou, H Murphy, JAD McLaughlin, NMD Brown, T McNally

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Surface-to-depth analysis of functionalized multi-wall carbon nanotubes, FMWCNT was achieved by the use of high resolution x-ray photoelectron spectroscopy (XPS) and secondary ion mass spectrometer (SIMS). The pristine nanotubes were functionalized through various steps. These included i) treatment in nitric acid followed by dispersion in dimethylformimide (DMF) and ii) further modification by the linking molecule, 1-ethyl-3-(3-dimethylaminopropyl carbodiimide), (EDC) through covalent attachment. Pristine nanotubes dispersed in DMF, possessed an atomic percentage of oxygen up to 3%, which more than doubled after treatment in nitric acid. After the second functionalization step, the atomic percent of oxygen was lowered relative to nitrogen as some oxygen was possibly displaced by the anchored molecules of EDC. In addition positive ions of CHNH, N2, CO, CH3NH, C2H3O, and negative ions of O, OH, and CN were detected by SIMS. On SIMS depth profiling, the intensity levels of both OH- and CN- ions were found to be steady throughout the 180 sec etch duration, indicating good in depth chemical functionalization of the carbon nanotube structure. Preliminary studies on functionalization of carbon nanotubes by atmospheric pressure dielectric barrier discharges (APDBD) are also reported. Copyright Taylor and Francis 2005
LanguageEnglish
Pages477
JournalFullerenes, Nanotubes and Carbon Nanostructures
Volume13
Issue number1
DOIs
Publication statusPublished - 2005

Fingerprint

Carbon Nanotubes
mass spectrometers
Carbon nanotubes
Mass spectrometers
carbon nanotubes
Ions
Nitric Acid
Nitric acid
Oxygen
Nanotubes
Ethyldimethylaminopropyl Carbodiimide
nitric acid
Molecules
Depth profiling
nanotubes
ions
oxygen
Carbon Monoxide
Photoelectron spectroscopy
Atmospheric pressure

Keywords

  • Functionalized carbon nanotubes
  • SIMS
  • XPS
  • biomedical sensors
  • dielectric barrier discharge

Cite this

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title = "Surface-to-Depth Analysis of Functionalized Multi-Wall Carbon Nanotubes (FMWCNTS)",
abstract = "Surface-to-depth analysis of functionalized multi-wall carbon nanotubes, FMWCNT was achieved by the use of high resolution x-ray photoelectron spectroscopy (XPS) and secondary ion mass spectrometer (SIMS). The pristine nanotubes were functionalized through various steps. These included i) treatment in nitric acid followed by dispersion in dimethylformimide (DMF) and ii) further modification by the linking molecule, 1-ethyl-3-(3-dimethylaminopropyl carbodiimide), (EDC) through covalent attachment. Pristine nanotubes dispersed in DMF, possessed an atomic percentage of oxygen up to 3{\%}, which more than doubled after treatment in nitric acid. After the second functionalization step, the atomic percent of oxygen was lowered relative to nitrogen as some oxygen was possibly displaced by the anchored molecules of EDC. In addition positive ions of CHNH, N2, CO, CH3NH, C2H3O, and negative ions of O, OH, and CN were detected by SIMS. On SIMS depth profiling, the intensity levels of both OH- and CN- ions were found to be steady throughout the 180 sec etch duration, indicating good in depth chemical functionalization of the carbon nanotube structure. Preliminary studies on functionalization of carbon nanotubes by atmospheric pressure dielectric barrier discharges (APDBD) are also reported. Copyright Taylor and Francis 2005",
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author = "TIT Okpalugo and P Papakonstantinou and H Murphy and JAD McLaughlin and NMD Brown and T McNally",
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Surface-to-Depth Analysis of Functionalized Multi-Wall Carbon Nanotubes (FMWCNTS). / Okpalugo, TIT; Papakonstantinou, P; Murphy, H; McLaughlin, JAD; Brown, NMD; McNally, T.

In: Fullerenes, Nanotubes and Carbon Nanostructures, Vol. 13, No. 1, 2005, p. 477.

Research output: Contribution to journalArticle

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AU - Okpalugo, TIT

AU - Papakonstantinou, P

AU - Murphy, H

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AU - McNally, T

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AB - Surface-to-depth analysis of functionalized multi-wall carbon nanotubes, FMWCNT was achieved by the use of high resolution x-ray photoelectron spectroscopy (XPS) and secondary ion mass spectrometer (SIMS). The pristine nanotubes were functionalized through various steps. These included i) treatment in nitric acid followed by dispersion in dimethylformimide (DMF) and ii) further modification by the linking molecule, 1-ethyl-3-(3-dimethylaminopropyl carbodiimide), (EDC) through covalent attachment. Pristine nanotubes dispersed in DMF, possessed an atomic percentage of oxygen up to 3%, which more than doubled after treatment in nitric acid. After the second functionalization step, the atomic percent of oxygen was lowered relative to nitrogen as some oxygen was possibly displaced by the anchored molecules of EDC. In addition positive ions of CHNH, N2, CO, CH3NH, C2H3O, and negative ions of O, OH, and CN were detected by SIMS. On SIMS depth profiling, the intensity levels of both OH- and CN- ions were found to be steady throughout the 180 sec etch duration, indicating good in depth chemical functionalization of the carbon nanotube structure. Preliminary studies on functionalization of carbon nanotubes by atmospheric pressure dielectric barrier discharges (APDBD) are also reported. Copyright Taylor and Francis 2005

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