Studies on Thermokinetic Methods (I) Determination of Reaction Rate Constants and Activation Energies by Calorimetry

Chang Li Xie; Quiduan Xu; Songsheng Qu; RK Owusu

Studies on Thermokinetic Methods (I) Determination of Reaction Rate Constants and Activation Energies by Calorimetry

Chang Li Xie, Quiduan Xu, Songsheng Qu, RK Owusu

Faculty Of Life & Health Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

The esterification rate constants of the acetic acid with the methanol and ethanol at various temperatures were determined by the flow microcalorimetry, while with the help of Arrhenius relation the activation energies of these reactions were determined. In order to check the reliability of method, the hydrolysis (reversal reaction of esterification) rate constants of methyl and ethyl acetates were determined, the results of experiments are consistent with results of calculation from the data of esterification experiments.

Original language	English
Pages (from-to)	363-369
Journal	Acta Physicochimica Sinica
Volume	2
Publication status	Published (in print/issue) - Apr 1986

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@article{990faf3f639e4aadbac8e7fa9846f272,

title = "Studies on Thermokinetic Methods (I) Determination of Reaction Rate Constants and Activation Energies by Calorimetry",

abstract = "The esterification rate constants of the acetic acid with the methanol and ethanol at various temperatures were determined by the flow microcalorimetry, while with the help of Arrhenius relation the activation energies of these reactions were determined. In order to check the reliability of method, the hydrolysis (reversal reaction of esterification) rate constants of methyl and ethyl acetates were determined, the results of experiments are consistent with results of calculation from the data of esterification experiments.",

author = "Xie, {Chang Li} and Quiduan Xu and Songsheng Qu and RK Owusu",

year = "1986",

month = apr,

language = "English",

volume = "2",

pages = "363--369",

journal = "Acta Physicochimica Sinica",

publisher = "Elsevier",

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T1 - Studies on Thermokinetic Methods (I) Determination of Reaction Rate Constants and Activation Energies by Calorimetry

AU - Xie, Chang Li

AU - Xu, Quiduan

AU - Qu, Songsheng

AU - Owusu, RK

PY - 1986/4

Y1 - 1986/4

N2 - The esterification rate constants of the acetic acid with the methanol and ethanol at various temperatures were determined by the flow microcalorimetry, while with the help of Arrhenius relation the activation energies of these reactions were determined. In order to check the reliability of method, the hydrolysis (reversal reaction of esterification) rate constants of methyl and ethyl acetates were determined, the results of experiments are consistent with results of calculation from the data of esterification experiments.

AB - The esterification rate constants of the acetic acid with the methanol and ethanol at various temperatures were determined by the flow microcalorimetry, while with the help of Arrhenius relation the activation energies of these reactions were determined. In order to check the reliability of method, the hydrolysis (reversal reaction of esterification) rate constants of methyl and ethyl acetates were determined, the results of experiments are consistent with results of calculation from the data of esterification experiments.

M3 - Article

VL - 2

SP - 363

EP - 369

JO - Acta Physicochimica Sinica

JF - Acta Physicochimica Sinica

ER -

Studies on Thermokinetic Methods (I) Determination of Reaction Rate Constants and Activation Energies by Calorimetry

Abstract

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