Stability of silicon–tin alloyed nanocrystals with high tin concentration synthesized by femtosecond laser plasma in liquid media

Mickaël Lozac’h, Marius Bürkle, Calum McDonald, Tetsuhiko Miyadera, Tomoyuki Koganezawa, Davide Mariotti, Vladimir Švrček

Research output: Contribution to journalArticlepeer-review

36 Downloads (Pure)


Nanocrystals have a great potential for future materials with tunable bandgap, due to their optical properties that are related with the material used, their sizes and their surface termination. Here, we concentrate on the silicon–tin alloy for photovoltaic applications due to their bandgap, lower than bulk Si, and also the possibility to activate direct band to band transition for high tin concentration. We synthesized silicon–tin alloy nanocrystals (SiSn-NCs) with diameter of about 2–3 nm by confined plasma technique employing a femtosecond laser irradiation on amorphous silicon–tin substrate submerged in liquid media. The tin concentration is estimated to be ∼17%, being the highest Sn concentration for SiSn-NCs reported so far. Our SiSn-NCs have a well-defined zinc-blend structure and, contrary to pure tin NCs, also an excellent thermal stability comparable to highly stable silicon NCs. We demonstrate by means of high resolution synchrotron XRD analysis (SPring 8) that the SiSn-NCs remain stable from room temperature up to 400∘C, with a relatively small expansion of the crystal lattice. The high thermal stability observed experimentally is rationalized by means of first-principle calculations.
Original languageEnglish
Article number7958
Pages (from-to)1-9
Number of pages9
JournalScientific Reports
Issue number1
Early online date17 May 2023
Publication statusPublished online - 17 May 2023

Bibliographical note

Funding Information:
This research was supported by the Japanese Promotion of Sciences (JSPS 13F03716 and 17F17815), Japan. M.B. and V.S. acknowledges the support by Kakenhi 20H02579 by the Japanese Promotion of Sciences (JSPS), Japan.

Publisher Copyright:
© 2023, The Author(s).


  • Electronic properties and materials
  • Nanoparticles
  • Structural properties
  • Synthesis and processing


Dive into the research topics of 'Stability of silicon–tin alloyed nanocrystals with high tin concentration synthesized by femtosecond laser plasma in liquid media'. Together they form a unique fingerprint.

Cite this