Preparation and characterization of a novel redox polymer based on salicyl-N-phenylene-1,4-diamine

J Davis, DH Vaughan, MF Cardosi

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The preparation of a novel redox polymer precursor based on the electropolymerization of salicyl-N-4-nitroaniline is described. The activation of the precursor sites to redox active phenylene diamine units through chemical reduction with tin is detailed. The resulting redox polymer was characterized by cyclic voltammetry, reflectance Fourier transform IR spectroscopy and scanning electron microscopy. The overall approach is evaluated with respect to the performance of the film and the structure of the coating after chemical modification.
LanguageEnglish
Pages213-218
JournalJournal of Electroanalytical Chemistry
Volume403
Issue number1-2
Publication statusPublished - Feb 1996

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Diamines
Polymers
Electropolymerization
Tin
Chemical modification
Cyclic voltammetry
Infrared spectroscopy
Fourier transforms
Chemical activation
Coatings
Scanning electron microscopy
Oxidation-Reduction

Cite this

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title = "Preparation and characterization of a novel redox polymer based on salicyl-N-phenylene-1,4-diamine",
abstract = "The preparation of a novel redox polymer precursor based on the electropolymerization of salicyl-N-4-nitroaniline is described. The activation of the precursor sites to redox active phenylene diamine units through chemical reduction with tin is detailed. The resulting redox polymer was characterized by cyclic voltammetry, reflectance Fourier transform IR spectroscopy and scanning electron microscopy. The overall approach is evaluated with respect to the performance of the film and the structure of the coating after chemical modification.",
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Preparation and characterization of a novel redox polymer based on salicyl-N-phenylene-1,4-diamine. / Davis, J; Vaughan, DH; Cardosi, MF.

In: Journal of Electroanalytical Chemistry, Vol. 403, No. 1-2, 02.1996, p. 213-218.

Research output: Contribution to journalArticle

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AB - The preparation of a novel redox polymer precursor based on the electropolymerization of salicyl-N-4-nitroaniline is described. The activation of the precursor sites to redox active phenylene diamine units through chemical reduction with tin is detailed. The resulting redox polymer was characterized by cyclic voltammetry, reflectance Fourier transform IR spectroscopy and scanning electron microscopy. The overall approach is evaluated with respect to the performance of the film and the structure of the coating after chemical modification.

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