Preparation and characterisation of rhenium(I)and platinum(IV) complexes of 2,6-bis(pyrazol-lylmethyl)pyridine and 2,6=bis(3,5-dimethylpyrazol-1-ylmethyl)pyridine. Crystalstructure of fac-[ReI(CO),(BMPz)]

KG Orrell; AG Osborne; Mateus Webba da Silva; MB Hursthouseb; SJ Coles

Preparation and characterisation of rhenium(I)and platinum(IV) complexes of 2,6-bis(pyrazol-lylmethyl)pyridine and 2,6=bis(3,5-dimethylpyrazol-1-ylmethyl)pyridine. Crystalstructure of fac-[ReI(CO),(BMPz)]

KG Orrell, AG Osborne, Mateus Webba da Silva, MB Hursthouseb, SJ Coles

Faculty Of Life & Health Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

Under mild conditions [ReX(CO),(THF),] reacts with pyrazolylmethylpyridines to form the complexesfat-[ReX(CO),(BPz)] and fat-[ReX(CO),(BMPz)] (X = Cl, Br, or I; BPz = 2,6-bis(pyrazol-l-ylmethyl)pyridine ; BMPz = 2,6-bis(3,5-dimethylpyrazol-1-ylmethyl)pyridine) that involve BPz and BMPz actingas non-fluxional bidentate chelate ligands. Under more severe reaction conditions fuc-[ReX(CO),(BPz)] isconverted to@-[Re(CO),(BPz)]X (X = Cl, Br, or I). Trimethylplatinum(IV)iodide reacts with BPz to formfuc-[PtMe,(BPz)]I. The crystal structure offac-[ReI(CO)3(BMPz)] confirms the bidentate chelate bonding ofBMPz with a N-Re-N angle of 85.8”.

Original language	English
Pages (from-to)	3003-3017
Journal	Polyhedron
Volume	16
Publication status	Published (in print/issue) - 1997

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@article{0609948f070244dcbcac4ad369636df4,

title = "Preparation and characterisation of rhenium(I)and platinum(IV) complexes of 2,6-bis(pyrazol-lylmethyl)pyridine and 2,6=bis(3,5-dimethylpyrazol-1-ylmethyl)pyridine. Crystalstructure of fac-[ReI(CO),(BMPz)]",

abstract = "Under mild conditions [ReX(CO),(THF),] reacts with pyrazolylmethylpyridines to form the complexesfat-[ReX(CO),(BPz)] and fat-[ReX(CO),(BMPz)] (X = Cl, Br, or I; BPz = 2,6-bis(pyrazol-l-ylmethyl)pyridine ; BMPz = 2,6-bis(3,5-dimethylpyrazol-1-ylmethyl)pyridine) that involve BPz and BMPz actingas non-fluxional bidentate chelate ligands. Under more severe reaction conditions fuc-[ReX(CO),(BPz)] isconverted to@-[Re(CO),(BPz)]X (X = Cl, Br, or I). Trimethylplatinum(IV)iodide reacts with BPz to formfuc-[PtMe,(BPz)]I. The crystal structure offac-[ReI(CO)3(BMPz)] confirms the bidentate chelate bonding ofBMPz with a N-Re-N angle of 85.8”.",

author = "KG Orrell and AG Osborne and {Webba da Silva}, Mateus and MB Hursthouseb and SJ Coles",

year = "1997",

language = "English",

volume = "16",

pages = "3003--3017",

journal = "Polyhedron",

issn = "1873-3719",

publisher = "Elsevier",

}

Preparation and characterisation of rhenium(I)and platinum(IV) complexes of 2,6-bis(pyrazol-lylmethyl)pyridine and 2,6=bis(3,5-dimethylpyrazol-1-ylmethyl)pyridine. Crystalstructure of fac-[ReI(CO),(BMPz)]. / Orrell, KG; Osborne, AG; Webba da Silva, Mateus et al.
In: Polyhedron, Vol. 16, 1997, p. 3003-3017.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Preparation and characterisation of rhenium(I)and platinum(IV) complexes of 2,6-bis(pyrazol-lylmethyl)pyridine and 2,6=bis(3,5-dimethylpyrazol-1-ylmethyl)pyridine. Crystalstructure of fac-[ReI(CO),(BMPz)]

AU - Orrell, KG

AU - Osborne, AG

AU - Webba da Silva, Mateus

AU - Hursthouseb, MB

AU - Coles, SJ

PY - 1997

Y1 - 1997

N2 - Under mild conditions [ReX(CO),(THF),] reacts with pyrazolylmethylpyridines to form the complexesfat-[ReX(CO),(BPz)] and fat-[ReX(CO),(BMPz)] (X = Cl, Br, or I; BPz = 2,6-bis(pyrazol-l-ylmethyl)pyridine ; BMPz = 2,6-bis(3,5-dimethylpyrazol-1-ylmethyl)pyridine) that involve BPz and BMPz actingas non-fluxional bidentate chelate ligands. Under more severe reaction conditions fuc-[ReX(CO),(BPz)] isconverted to@-[Re(CO),(BPz)]X (X = Cl, Br, or I). Trimethylplatinum(IV)iodide reacts with BPz to formfuc-[PtMe,(BPz)]I. The crystal structure offac-[ReI(CO)3(BMPz)] confirms the bidentate chelate bonding ofBMPz with a N-Re-N angle of 85.8”.

AB - Under mild conditions [ReX(CO),(THF),] reacts with pyrazolylmethylpyridines to form the complexesfat-[ReX(CO),(BPz)] and fat-[ReX(CO),(BMPz)] (X = Cl, Br, or I; BPz = 2,6-bis(pyrazol-l-ylmethyl)pyridine ; BMPz = 2,6-bis(3,5-dimethylpyrazol-1-ylmethyl)pyridine) that involve BPz and BMPz actingas non-fluxional bidentate chelate ligands. Under more severe reaction conditions fuc-[ReX(CO),(BPz)] isconverted to@-[Re(CO),(BPz)]X (X = Cl, Br, or I). Trimethylplatinum(IV)iodide reacts with BPz to formfuc-[PtMe,(BPz)]I. The crystal structure offac-[ReI(CO)3(BMPz)] confirms the bidentate chelate bonding ofBMPz with a N-Re-N angle of 85.8”.

M3 - Article

SN - 1873-3719

VL - 16

SP - 3003

EP - 3017

JO - Polyhedron

JF - Polyhedron

ER -