Plasma-controlled metal catalyst saturation and the initial stage of carbon nanostructure array growth

I. Levchenko, K. Ostrikov, D Mariotti, AB Murphy

    Research output: Contribution to journalArticle

    13 Citations (Scopus)

    Abstract

    The kinetics of the nucleation and growth of carbon nanotube and nanocone arrays on Ni catalyst nanoparticles on a silicon surface exposed to a low-temperature plasma are investigated numerically, using a complex model that includes surface diffusion and ion motion equations. It is found that the degree of ionization of the carbon flux strongly affects the kinetics of nanotube and nanocone nucleation on partially saturated catalyst patterns. The use of highly ionized carbon flux allows formation of a nanotube array with a very narrow height distribution of half-width 7 nm. Similar results are obtained for carbon nanocone arrays, with an even narrower height distribution, using a highly ionized carbon flux. As the deposition time increases, nanostructure arrays develop without widening the height distribution when the flux ionization degree is high, in contrast to the fairly broad nanostructure height distributions obtained when the degree of ionization is low. (C) 2008 American Institute of Physics. [DOI: 10.1063/1.2996272]
    LanguageEnglish
    Pages073308-1
    JournalJournal of Applied Physics
    Volume104
    Issue number7
    Early online date14 Oct 2008
    DOIs
    Publication statusE-pub ahead of print - 14 Oct 2008

    Fingerprint

    saturation
    catalysts
    carbon
    ionization
    metals
    nanotubes
    nucleation
    ion motion
    kinetics
    cold plasmas
    surface diffusion
    equations of motion
    carbon nanotubes
    nanoparticles
    silicon

    Cite this

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    title = "Plasma-controlled metal catalyst saturation and the initial stage of carbon nanostructure array growth",
    abstract = "The kinetics of the nucleation and growth of carbon nanotube and nanocone arrays on Ni catalyst nanoparticles on a silicon surface exposed to a low-temperature plasma are investigated numerically, using a complex model that includes surface diffusion and ion motion equations. It is found that the degree of ionization of the carbon flux strongly affects the kinetics of nanotube and nanocone nucleation on partially saturated catalyst patterns. The use of highly ionized carbon flux allows formation of a nanotube array with a very narrow height distribution of half-width 7 nm. Similar results are obtained for carbon nanocone arrays, with an even narrower height distribution, using a highly ionized carbon flux. As the deposition time increases, nanostructure arrays develop without widening the height distribution when the flux ionization degree is high, in contrast to the fairly broad nanostructure height distributions obtained when the degree of ionization is low. (C) 2008 American Institute of Physics. [DOI: 10.1063/1.2996272]",
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    Plasma-controlled metal catalyst saturation and the initial stage of carbon nanostructure array growth. / Levchenko, I.; Ostrikov, K.; Mariotti, D; Murphy, AB.

    In: Journal of Applied Physics, Vol. 104, No. 7, 14.10.2008, p. 073308-1.

    Research output: Contribution to journalArticle

    TY - JOUR

    T1 - Plasma-controlled metal catalyst saturation and the initial stage of carbon nanostructure array growth

    AU - Levchenko, I.

    AU - Ostrikov, K.

    AU - Mariotti, D

    AU - Murphy, AB

    PY - 2008/10/14

    Y1 - 2008/10/14

    N2 - The kinetics of the nucleation and growth of carbon nanotube and nanocone arrays on Ni catalyst nanoparticles on a silicon surface exposed to a low-temperature plasma are investigated numerically, using a complex model that includes surface diffusion and ion motion equations. It is found that the degree of ionization of the carbon flux strongly affects the kinetics of nanotube and nanocone nucleation on partially saturated catalyst patterns. The use of highly ionized carbon flux allows formation of a nanotube array with a very narrow height distribution of half-width 7 nm. Similar results are obtained for carbon nanocone arrays, with an even narrower height distribution, using a highly ionized carbon flux. As the deposition time increases, nanostructure arrays develop without widening the height distribution when the flux ionization degree is high, in contrast to the fairly broad nanostructure height distributions obtained when the degree of ionization is low. (C) 2008 American Institute of Physics. [DOI: 10.1063/1.2996272]

    AB - The kinetics of the nucleation and growth of carbon nanotube and nanocone arrays on Ni catalyst nanoparticles on a silicon surface exposed to a low-temperature plasma are investigated numerically, using a complex model that includes surface diffusion and ion motion equations. It is found that the degree of ionization of the carbon flux strongly affects the kinetics of nanotube and nanocone nucleation on partially saturated catalyst patterns. The use of highly ionized carbon flux allows formation of a nanotube array with a very narrow height distribution of half-width 7 nm. Similar results are obtained for carbon nanocone arrays, with an even narrower height distribution, using a highly ionized carbon flux. As the deposition time increases, nanostructure arrays develop without widening the height distribution when the flux ionization degree is high, in contrast to the fairly broad nanostructure height distributions obtained when the degree of ionization is low. (C) 2008 American Institute of Physics. [DOI: 10.1063/1.2996272]

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