Expanding the portfolio of tribo-positive materials: aniline formaldehyde condensates for high charge density triboelectric nanogenerators

Pengfei Zhao, Navneet Soin, Amit Kumar, Lin Shi, Shaoliang Guan, Christos Tsonos, Ziong Yu, Sekhar C. Ray, James McLaughlin, Zhigang Zhu, Erping Zhou, Junfeng Geng, Chan H. See, Jikui Luo

Research output: Contribution to journalArticle

Abstract

The rapid uptake of energy harvesting triboelectric nanogenerators (TENGs) for self-powered electronics requires the development of high-performance tribo-materials capable of providing large power outputs. This work reports on the synthesis and use of aniline formaldehyde resin (AFR) for energy-harvesting applications. The facile, acidic-medium reaction between aniline and formaldehyde produces the aniline-formaldehyde condensate, which upon an in-vacuo high temperature curing step provides smooth AFR films with abundant nitrogen and oxygen surface functional groups which can acquire a tribo-positive charge and thus endow AFR with a significantly higher positive tribo-polarity than the existing state-of-art polyamide-6 (PA6). A TENG comprising of optimized thin-layered AFR against a polytetrafluoroethylene (PTFE) film produced a peak-to-peak voltage of up to ~1,000 V, a current density of ~65 mA m-2, a transferred charge density of ~200 μC m-2 and an instantaneous power output (energy pulse) of ~11 W m-2 (28.1 μJ cycle-1), respectively. The suitability of AFR was further supported through the Kelvin probe force microscopy (KPFM) measurements, which reveal a significantly higher average surface potential value of 1.147 V for AFR as compared to 0.87 V for PA6 and a step-by-step increase of the surface potential with the increase of energy generation cycles. The work not only proposes a novel and scalable mouldable AFR synthesis process but also expands with excellent prospects, the current portfolio of tribo-positive materials for triboelectric energy harvesting applications.
LanguageEnglish
Article number104291
JournalNano Energy
Volume67
Early online date14 Nov 2019
DOIs
Publication statusPublished - 1 Jan 2020

Fingerprint

Aniline
Charge density
Formaldehyde
Resins
Energy harvesting
Surface potential
Polyamides
aniline
Polytetrafluoroethylene
Polytetrafluoroethylenes
Functional groups
Curing
Microscopic examination
Current density
Electronic equipment
Nitrogen
Oxygen
Electric potential

Keywords

  • Aniline formaldehyde resins
  • KPFM
  • Surface potential
  • Tribo-positive polymers
  • Triboelectric nanogenerators

Cite this

Zhao, Pengfei ; Soin, Navneet ; Kumar, Amit ; Shi, Lin ; Guan, Shaoliang ; Tsonos, Christos ; Yu, Ziong ; Ray, Sekhar C. ; McLaughlin, James ; Zhu, Zhigang ; Zhou, Erping ; Geng, Junfeng ; See, Chan H. ; Luo, Jikui. / Expanding the portfolio of tribo-positive materials: aniline formaldehyde condensates for high charge density triboelectric nanogenerators. In: Nano Energy. 2020 ; Vol. 67.
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Expanding the portfolio of tribo-positive materials: aniline formaldehyde condensates for high charge density triboelectric nanogenerators. / Zhao, Pengfei; Soin, Navneet; Kumar, Amit; Shi, Lin; Guan, Shaoliang ; Tsonos, Christos; Yu, Ziong; Ray, Sekhar C.; McLaughlin, James; Zhu, Zhigang; Zhou, Erping; Geng, Junfeng; See, Chan H.; Luo, Jikui.

In: Nano Energy, Vol. 67, 104291, 01.01.2020.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Expanding the portfolio of tribo-positive materials: aniline formaldehyde condensates for high charge density triboelectric nanogenerators

AU - Zhao, Pengfei

AU - Soin, Navneet

AU - Kumar, Amit

AU - Shi, Lin

AU - Guan, Shaoliang

AU - Tsonos, Christos

AU - Yu, Ziong

AU - Ray, Sekhar C.

AU - McLaughlin, James

AU - Zhu, Zhigang

AU - Zhou, Erping

AU - Geng, Junfeng

AU - See, Chan H.

AU - Luo, Jikui

PY - 2020/1/1

Y1 - 2020/1/1

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AB - The rapid uptake of energy harvesting triboelectric nanogenerators (TENGs) for self-powered electronics requires the development of high-performance tribo-materials capable of providing large power outputs. This work reports on the synthesis and use of aniline formaldehyde resin (AFR) for energy-harvesting applications. The facile, acidic-medium reaction between aniline and formaldehyde produces the aniline-formaldehyde condensate, which upon an in-vacuo high temperature curing step provides smooth AFR films with abundant nitrogen and oxygen surface functional groups which can acquire a tribo-positive charge and thus endow AFR with a significantly higher positive tribo-polarity than the existing state-of-art polyamide-6 (PA6). A TENG comprising of optimized thin-layered AFR against a polytetrafluoroethylene (PTFE) film produced a peak-to-peak voltage of up to ~1,000 V, a current density of ~65 mA m-2, a transferred charge density of ~200 μC m-2 and an instantaneous power output (energy pulse) of ~11 W m-2 (28.1 μJ cycle-1), respectively. The suitability of AFR was further supported through the Kelvin probe force microscopy (KPFM) measurements, which reveal a significantly higher average surface potential value of 1.147 V for AFR as compared to 0.87 V for PA6 and a step-by-step increase of the surface potential with the increase of energy generation cycles. The work not only proposes a novel and scalable mouldable AFR synthesis process but also expands with excellent prospects, the current portfolio of tribo-positive materials for triboelectric energy harvesting applications.

KW - Aniline formaldehyde resins

KW - KPFM

KW - Surface potential

KW - Tribo-positive polymers

KW - Triboelectric nanogenerators

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