Ephedrine-copper-carbon interactions: An electroanalytical investigation

M Platts, RB Smith, N Mould, J Davis

    Research output: Contribution to journalArticle

    10 Citations (Scopus)

    Abstract

    The electrochemical behaviour of ephedrine at carbon fibre electrodes has been investigated as a preliminary step in the development of a decentralised sensor for the alkaloid. The reaction pathway has been examined and key intermediates (principally benzaldehyde) resulting from the electrode processes identified by complementary chromatographic (GC-MS) and spectroscopic methods (NMR). A novel detection strategy has been developed in which the in situ manipulation of pH at the electrode interface induces a shift in the oxidation potential of the ephedrine to a region where it can be readily quantified. The electrochemical basis from which local pH can be controlled is outlined and the detection methodology is examined with respect to the influence of potential interferences (ascorbate and urate). (c) 2006 Published by Elsevier B.V.
    Original languageEnglish
    Pages (from-to)633-637
    JournalElectrochemistry Communications
    Volume8
    Issue number4
    DOIs
    Publication statusPublished - Apr 2006

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