Electrochemical characterisation of novel water-soluble ruthenocene complexes: An anion-dependent response

NS Lawrence; CE Banks; GJ Tustin; TGJ Jones; RB Smith; J Davis; JD Wadhawan

doi:10.1016/j.elecom.2007.02.005

Electrochemical characterisation of novel water-soluble ruthenocene complexes: An anion-dependent response

NS Lawrence
, CE Banks
, GJ Tustin
, TGJ Jones
, RB Smith
, J Davis
, JD Wadhawan

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The synthesis and voltammetric exploration of water-soluble ruthenocene sulfonate is reported. H-1 and C-13 NMR, mass spectroscopy and elemental analysis data are given to confirm the successful synthesis of this novel compound. Furthermore, it is found that the cyclic voltammetric response is strongly dependent on the size of anion in solution. Sodium toluene sulfonate is found to be capable of forming a charge-transfer complex with the oxidized ruthenocenium ion. In the presence of all other anions, follow-on reactions are observed. (c) 2007 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	1451-1455
Journal	Electrochemistry Communications
Volume	9
Issue number	7
DOIs	https://doi.org/10.1016/j.elecom.2007.02.005
Publication status	Published (in print/issue) - Jul 2007

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10.1016/j.elecom.2007.02.005

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title = "Electrochemical characterisation of novel water-soluble ruthenocene complexes: An anion-dependent response",

abstract = "The synthesis and voltammetric exploration of water-soluble ruthenocene sulfonate is reported. H-1 and C-13 NMR, mass spectroscopy and elemental analysis data are given to confirm the successful synthesis of this novel compound. Furthermore, it is found that the cyclic voltammetric response is strongly dependent on the size of anion in solution. Sodium toluene sulfonate is found to be capable of forming a charge-transfer complex with the oxidized ruthenocenium ion. In the presence of all other anions, follow-on reactions are observed. (c) 2007 Elsevier B.V. All rights reserved.",

author = "NS Lawrence and CE Banks and GJ Tustin and TGJ Jones and RB Smith and J Davis and JD Wadhawan",

year = "2007",

month = jul,

doi = "10.1016/j.elecom.2007.02.005",

language = "English",

volume = "9",

pages = "1451--1455",

journal = "Electrochemistry Communications",

issn = "1388-2481",

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TY - JOUR

T1 - Electrochemical characterisation of novel water-soluble ruthenocene complexes: An anion-dependent response

AU - Lawrence, NS

AU - Banks, CE

AU - Tustin, GJ

AU - Jones, TGJ

AU - Smith, RB

AU - Davis, J

AU - Wadhawan, JD

PY - 2007/7

Y1 - 2007/7

N2 - The synthesis and voltammetric exploration of water-soluble ruthenocene sulfonate is reported. H-1 and C-13 NMR, mass spectroscopy and elemental analysis data are given to confirm the successful synthesis of this novel compound. Furthermore, it is found that the cyclic voltammetric response is strongly dependent on the size of anion in solution. Sodium toluene sulfonate is found to be capable of forming a charge-transfer complex with the oxidized ruthenocenium ion. In the presence of all other anions, follow-on reactions are observed. (c) 2007 Elsevier B.V. All rights reserved.

AB - The synthesis and voltammetric exploration of water-soluble ruthenocene sulfonate is reported. H-1 and C-13 NMR, mass spectroscopy and elemental analysis data are given to confirm the successful synthesis of this novel compound. Furthermore, it is found that the cyclic voltammetric response is strongly dependent on the size of anion in solution. Sodium toluene sulfonate is found to be capable of forming a charge-transfer complex with the oxidized ruthenocenium ion. In the presence of all other anions, follow-on reactions are observed. (c) 2007 Elsevier B.V. All rights reserved.

U2 - 10.1016/j.elecom.2007.02.005

DO - 10.1016/j.elecom.2007.02.005

M3 - Article

SN - 1388-2481

VL - 9

SP - 1451

EP - 1455

JO - Electrochemistry Communications

JF - Electrochemistry Communications

IS - 7

ER -

Electrochemical characterisation of novel water-soluble ruthenocene complexes: An anion-dependent response

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