Electrochemical characterisation of novel water-soluble ruthenocene complexes: An anion-dependent response

NS Lawrence, CE Banks, GJ Tustin, TGJ Jones, RB Smith, J Davis, JD Wadhawan

    Research output: Contribution to journalArticle

    2 Citations (Scopus)

    Abstract

    The synthesis and voltammetric exploration of water-soluble ruthenocene sulfonate is reported. H-1 and C-13 NMR, mass spectroscopy and elemental analysis data are given to confirm the successful synthesis of this novel compound. Furthermore, it is found that the cyclic voltammetric response is strongly dependent on the size of anion in solution. Sodium toluene sulfonate is found to be capable of forming a charge-transfer complex with the oxidized ruthenocenium ion. In the presence of all other anions, follow-on reactions are observed. (c) 2007 Elsevier B.V. All rights reserved.
    LanguageEnglish
    Pages1451-1455
    JournalElectrochemistry Communications
    Volume9
    Issue number7
    DOIs
    Publication statusPublished - Jul 2007

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    Anions
    Water
    Toluene
    Charge transfer
    Sodium
    Nuclear magnetic resonance
    Spectroscopy
    Ions
    Chemical analysis
    ruthenocene

    Cite this

    Lawrence, NS ; Banks, CE ; Tustin, GJ ; Jones, TGJ ; Smith, RB ; Davis, J ; Wadhawan, JD. / Electrochemical characterisation of novel water-soluble ruthenocene complexes: An anion-dependent response. In: Electrochemistry Communications. 2007 ; Vol. 9, No. 7. pp. 1451-1455.
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    abstract = "The synthesis and voltammetric exploration of water-soluble ruthenocene sulfonate is reported. H-1 and C-13 NMR, mass spectroscopy and elemental analysis data are given to confirm the successful synthesis of this novel compound. Furthermore, it is found that the cyclic voltammetric response is strongly dependent on the size of anion in solution. Sodium toluene sulfonate is found to be capable of forming a charge-transfer complex with the oxidized ruthenocenium ion. In the presence of all other anions, follow-on reactions are observed. (c) 2007 Elsevier B.V. All rights reserved.",
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    Electrochemical characterisation of novel water-soluble ruthenocene complexes: An anion-dependent response. / Lawrence, NS; Banks, CE; Tustin, GJ; Jones, TGJ; Smith, RB; Davis, J; Wadhawan, JD.

    In: Electrochemistry Communications, Vol. 9, No. 7, 07.2007, p. 1451-1455.

    Research output: Contribution to journalArticle

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    AU - Lawrence, NS

    AU - Banks, CE

    AU - Tustin, GJ

    AU - Jones, TGJ

    AU - Smith, RB

    AU - Davis, J

    AU - Wadhawan, JD

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