Dimethylsubstituted pyrroles: A new approach to protective polymers

LAA Newton; S Sing U; R Leslie; J Davis

doi:10.1016/j.elecom.2009.02.020

Dimethylsubstituted pyrroles: A new approach to protective polymers

LAA Newton, S Sing U, R Leslie, J Davis

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The development of sacrificial or protective films based on dimethylpyrrole analogues is described. The design considerations required for successful electropolymerisation of the monomer and the subsequent, selective dissolution of the film is described. A general synthetic strategy is presented for the formation of a diverse range of bifunctional monomers which, when polymerised, can be subsequently removed after exposure to hydroxylamine under neutral aqueous conditions at room temperature. Film formation and removal has been studied using cyclic voltammetry and electrochemical quartz crystal microbalance (EQCM) studies.

Original language	English
Pages (from-to)	929-932
Journal	Electrochemistry Communications
Volume	11
Issue number	4
DOIs	https://doi.org/10.1016/j.elecom.2009.02.020
Publication status	Published (in print/issue) - Apr 2009

Keywords

Pyrrole
Acetonylacetone
Template
Protective group
Electropolymerisation
Polymer

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10.1016/j.elecom.2009.02.020

http://uir.ulster.ac.uk/11894/1/JDavis_Dimethylsubstituted_pyrroles.pdf

Cite this

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title = "Dimethylsubstituted pyrroles: A new approach to protective polymers",

abstract = "The development of sacrificial or protective films based on dimethylpyrrole analogues is described. The design considerations required for successful electropolymerisation of the monomer and the subsequent, selective dissolution of the film is described. A general synthetic strategy is presented for the formation of a diverse range of bifunctional monomers which, when polymerised, can be subsequently removed after exposure to hydroxylamine under neutral aqueous conditions at room temperature. Film formation and removal has been studied using cyclic voltammetry and electrochemical quartz crystal microbalance (EQCM) studies.",

keywords = "Pyrrole, Acetonylacetone, Template, Protective group, Electropolymerisation, Polymer",

author = "LAA Newton and {Sing U}, S and R Leslie and J Davis",

year = "2009",

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language = "English",

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journal = "Electrochemistry Communications",

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T1 - Dimethylsubstituted pyrroles: A new approach to protective polymers

AU - Newton, LAA

AU - Sing U, S

AU - Leslie, R

AU - Davis, J

PY - 2009/4

Y1 - 2009/4

N2 - The development of sacrificial or protective films based on dimethylpyrrole analogues is described. The design considerations required for successful electropolymerisation of the monomer and the subsequent, selective dissolution of the film is described. A general synthetic strategy is presented for the formation of a diverse range of bifunctional monomers which, when polymerised, can be subsequently removed after exposure to hydroxylamine under neutral aqueous conditions at room temperature. Film formation and removal has been studied using cyclic voltammetry and electrochemical quartz crystal microbalance (EQCM) studies.

AB - The development of sacrificial or protective films based on dimethylpyrrole analogues is described. The design considerations required for successful electropolymerisation of the monomer and the subsequent, selective dissolution of the film is described. A general synthetic strategy is presented for the formation of a diverse range of bifunctional monomers which, when polymerised, can be subsequently removed after exposure to hydroxylamine under neutral aqueous conditions at room temperature. Film formation and removal has been studied using cyclic voltammetry and electrochemical quartz crystal microbalance (EQCM) studies.

KW - Pyrrole

KW - Acetonylacetone

KW - Template

KW - Protective group

KW - Electropolymerisation

KW - Polymer

U2 - 10.1016/j.elecom.2009.02.020

DO - 10.1016/j.elecom.2009.02.020

M3 - Article

SN - 1388-2481

VL - 11

SP - 929

EP - 932

JO - Electrochemistry Communications

JF - Electrochemistry Communications

IS - 4

ER -

Dimethylsubstituted pyrroles: A new approach to protective polymers

Abstract

Keywords

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