Dimethylsubstituted pyrroles: A new approach to protective polymers

LAA Newton, S Sing U, R Leslie, J Davis

    Research output: Contribution to journalArticle

    Abstract

    The development of sacrificial or protective films based on dimethylpyrrole analogues is described. The design considerations required for successful electropolymerisation of the monomer and the subsequent, selective dissolution of the film is described. A general synthetic strategy is presented for the formation of a diverse range of bifunctional monomers which, when polymerised, can be subsequently removed after exposure to hydroxylamine under neutral aqueous conditions at room temperature. Film formation and removal has been studied using cyclic voltammetry and electrochemical quartz crystal microbalance (EQCM) studies.
    LanguageEnglish
    Pages929-932
    JournalElectrochemistry Communications
    Volume11
    Issue number4
    DOIs
    Publication statusPublished - Apr 2009

    Fingerprint

    Pyrroles
    Polymers
    Monomers
    Hydroxylamine
    Electropolymerization
    Quartz crystal microbalances
    Protective coatings
    Cyclic voltammetry
    Dissolution
    Temperature

    Keywords

    • Pyrrole
    • Acetonylacetone
    • Template
    • Protective group
    • Electropolymerisation
    • Polymer

    Cite this

    Newton, LAA ; Sing U, S ; Leslie, R ; Davis, J. / Dimethylsubstituted pyrroles: A new approach to protective polymers. In: Electrochemistry Communications. 2009 ; Vol. 11, No. 4. pp. 929-932.
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    Dimethylsubstituted pyrroles: A new approach to protective polymers. / Newton, LAA; Sing U, S; Leslie, R; Davis, J.

    In: Electrochemistry Communications, Vol. 11, No. 4, 04.2009, p. 929-932.

    Research output: Contribution to journalArticle

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    AU - Leslie, R

    AU - Davis, J

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    KW - Acetonylacetone

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    KW - Protective group

    KW - Electropolymerisation

    KW - Polymer

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