A study of the electrospray ionisation of selected coumarin derivatives and their subsequent fragmentation using an ion trap mass spectrometer

S Concannon, VN Ramachandran, Franklin Smyth

    Research output: Contribution to journalArticle

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    Abstract

    The electrospray ionisation (ESI) of selected coumarin derivatives and their subsequent fragmentation using an ion trap mass spectrometer have been investigated. Sequential product ion fragmentation experiments (MSn) were performed in order to elucidate the degradation pathways for these compounds. A comparison was also made between these ESI spectra and those obtained under electron impact (EI) conditions. The data presented in this paper provides useful information on the effect of different substituents on the ionisation/fragmentation processes and can be used in the characterisation of these compounds. Copyright (C) 2000 John Wiley & Sons, Ltd.
    LanguageEnglish
    Pages1157-1166
    JournalRapid Communications in Mass Spectrometry
    Volume14
    Issue number14
    Publication statusPublished - 2000

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    Coumarins
    Electrospray ionization
    Mass spectrometers
    Ions
    Ionization
    Degradation
    Electrons
    Experiments

    Cite this

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    abstract = "The electrospray ionisation (ESI) of selected coumarin derivatives and their subsequent fragmentation using an ion trap mass spectrometer have been investigated. Sequential product ion fragmentation experiments (MSn) were performed in order to elucidate the degradation pathways for these compounds. A comparison was also made between these ESI spectra and those obtained under electron impact (EI) conditions. The data presented in this paper provides useful information on the effect of different substituents on the ionisation/fragmentation processes and can be used in the characterisation of these compounds. Copyright (C) 2000 John Wiley & Sons, Ltd.",
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    A study of the electrospray ionisation of selected coumarin derivatives and their subsequent fragmentation using an ion trap mass spectrometer. / Concannon, S; Ramachandran, VN; Smyth, Franklin.

    In: Rapid Communications in Mass Spectrometry, Vol. 14, No. 14, 2000, p. 1157-1166.

    Research output: Contribution to journalArticle

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    AU - Concannon, S

    AU - Ramachandran, VN

    AU - Smyth, Franklin

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    AB - The electrospray ionisation (ESI) of selected coumarin derivatives and their subsequent fragmentation using an ion trap mass spectrometer have been investigated. Sequential product ion fragmentation experiments (MSn) were performed in order to elucidate the degradation pathways for these compounds. A comparison was also made between these ESI spectra and those obtained under electron impact (EI) conditions. The data presented in this paper provides useful information on the effect of different substituents on the ionisation/fragmentation processes and can be used in the characterisation of these compounds. Copyright (C) 2000 John Wiley & Sons, Ltd.

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    JO - Rapid Communications in Mass Spectrometry

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