The electrospray ionisation (ESI) of selected hemiterpenoid and dimeric coumarin derivatives and their subsequent fragmentation using an ion trap mass spectrometer are reported and discussed. Sequential product ion fragmentation experiments (MSn) were performed in order to elucidate the degradation pathways for these compounds. The results illustrate that the observed characteristic fragmentation patterns are of considerable utility in the application of ESI mass spectrometry to the characterisation of this class of compounds. Copyright (C) 2000 John Wiley & Sons, Ltd.
title = "A study of the electrospray ionisation and ion trap fragmentation of hemiterpenoid and dimeric coumarin derivatives",
abstract = "The electrospray ionisation (ESI) of selected hemiterpenoid and dimeric coumarin derivatives and their subsequent fragmentation using an ion trap mass spectrometer are reported and discussed. Sequential product ion fragmentation experiments (MSn) were performed in order to elucidate the degradation pathways for these compounds. The results illustrate that the observed characteristic fragmentation patterns are of considerable utility in the application of ESI mass spectrometry to the characterisation of this class of compounds. Copyright (C) 2000 John Wiley & Sons, Ltd.",
author = "S Concannon and VN Ramachandran and Franklin Smyth",
year = "2000",
language = "English",
volume = "14",
pages = "2260--2270",
journal = "Rapid Communications in Mass Spectrometry",
Research output: Contribution to journal › Article
TY - JOUR
T1 - A study of the electrospray ionisation and ion trap fragmentation of hemiterpenoid and dimeric coumarin derivatives
AU - Concannon, S
AU - Ramachandran, VN
AU - Smyth, Franklin
PY - 2000
Y1 - 2000
N2 - The electrospray ionisation (ESI) of selected hemiterpenoid and dimeric coumarin derivatives and their subsequent fragmentation using an ion trap mass spectrometer are reported and discussed. Sequential product ion fragmentation experiments (MSn) were performed in order to elucidate the degradation pathways for these compounds. The results illustrate that the observed characteristic fragmentation patterns are of considerable utility in the application of ESI mass spectrometry to the characterisation of this class of compounds. Copyright (C) 2000 John Wiley & Sons, Ltd.
AB - The electrospray ionisation (ESI) of selected hemiterpenoid and dimeric coumarin derivatives and their subsequent fragmentation using an ion trap mass spectrometer are reported and discussed. Sequential product ion fragmentation experiments (MSn) were performed in order to elucidate the degradation pathways for these compounds. The results illustrate that the observed characteristic fragmentation patterns are of considerable utility in the application of ESI mass spectrometry to the characterisation of this class of compounds. Copyright (C) 2000 John Wiley & Sons, Ltd.