A model for lead, zinc, and copper in lakes

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Abstract

We present a budget for lead, zinc, and copper in Lough Neagh, Northern Ireland, and use the results from this and seven other lakes in Europe and the United States to develop two simple, generic models for heavy metals in lake water. The models, based on retention coefficient and sedimentation coefficient, are assessed by comparing the modeled and measured steady-state lake concentrations. The results show that deposition from the atmosphere is an important source of contamination of the lakes by Pb (56.3% of total inputs) and Zn (34.8%), but not Cu (8.3%). The mean retention coefficient in five of the lakes is 0.70 (RSD = 29%), 0.72 (24%), and 0.24 (133%) for Pb, Zn, and Cu, respectively; mean total residence time is 0.21 (RSD = 64%), 0.36 (61%), and 0.77 (97%) yr; and mean sedimentation residence time 0.34 (RSD = 73%), 0.91 (99%), and 0.05 (95%) yr. The goodness of fit of the two models are similar, with root mean square error of prediction of +/-0.14, 1.9, and 1.6 mug L-1 for Pb, Zn, and Cu, respectively. The magnitude of the errors in relation to the ranges of concentration suggests that the models for Pb and Zn can be used as fate models for these metals in lake water.
LanguageEnglish
Pages2256-2264
JournalLimnology and Oceanography
Volume49
Issue number6
Publication statusPublished - Nov 2004

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zinc
copper
lake
lake water
residence time
sedimentation
heavy metal
atmosphere
metal
prediction

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Rippey, B ; Rose, CL ; Douglas, RW. / A model for lead, zinc, and copper in lakes. 2004 ; Vol. 49, No. 6. pp. 2256-2264.
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abstract = "We present a budget for lead, zinc, and copper in Lough Neagh, Northern Ireland, and use the results from this and seven other lakes in Europe and the United States to develop two simple, generic models for heavy metals in lake water. The models, based on retention coefficient and sedimentation coefficient, are assessed by comparing the modeled and measured steady-state lake concentrations. The results show that deposition from the atmosphere is an important source of contamination of the lakes by Pb (56.3{\%} of total inputs) and Zn (34.8{\%}), but not Cu (8.3{\%}). The mean retention coefficient in five of the lakes is 0.70 (RSD = 29{\%}), 0.72 (24{\%}), and 0.24 (133{\%}) for Pb, Zn, and Cu, respectively; mean total residence time is 0.21 (RSD = 64{\%}), 0.36 (61{\%}), and 0.77 (97{\%}) yr; and mean sedimentation residence time 0.34 (RSD = 73{\%}), 0.91 (99{\%}), and 0.05 (95{\%}) yr. The goodness of fit of the two models are similar, with root mean square error of prediction of +/-0.14, 1.9, and 1.6 mug L-1 for Pb, Zn, and Cu, respectively. The magnitude of the errors in relation to the ranges of concentration suggests that the models for Pb and Zn can be used as fate models for these metals in lake water.",
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Rippey, B, Rose, CL & Douglas, RW 2004, 'A model for lead, zinc, and copper in lakes', vol. 49, no. 6, pp. 2256-2264.

A model for lead, zinc, and copper in lakes. / Rippey, B; Rose, CL; Douglas, RW.

Vol. 49, No. 6, 11.2004, p. 2256-2264.

Research output: Contribution to journalArticle

TY - JOUR

T1 - A model for lead, zinc, and copper in lakes

AU - Rippey, B

AU - Rose, CL

AU - Douglas, RW

PY - 2004/11

Y1 - 2004/11

N2 - We present a budget for lead, zinc, and copper in Lough Neagh, Northern Ireland, and use the results from this and seven other lakes in Europe and the United States to develop two simple, generic models for heavy metals in lake water. The models, based on retention coefficient and sedimentation coefficient, are assessed by comparing the modeled and measured steady-state lake concentrations. The results show that deposition from the atmosphere is an important source of contamination of the lakes by Pb (56.3% of total inputs) and Zn (34.8%), but not Cu (8.3%). The mean retention coefficient in five of the lakes is 0.70 (RSD = 29%), 0.72 (24%), and 0.24 (133%) for Pb, Zn, and Cu, respectively; mean total residence time is 0.21 (RSD = 64%), 0.36 (61%), and 0.77 (97%) yr; and mean sedimentation residence time 0.34 (RSD = 73%), 0.91 (99%), and 0.05 (95%) yr. The goodness of fit of the two models are similar, with root mean square error of prediction of +/-0.14, 1.9, and 1.6 mug L-1 for Pb, Zn, and Cu, respectively. The magnitude of the errors in relation to the ranges of concentration suggests that the models for Pb and Zn can be used as fate models for these metals in lake water.

AB - We present a budget for lead, zinc, and copper in Lough Neagh, Northern Ireland, and use the results from this and seven other lakes in Europe and the United States to develop two simple, generic models for heavy metals in lake water. The models, based on retention coefficient and sedimentation coefficient, are assessed by comparing the modeled and measured steady-state lake concentrations. The results show that deposition from the atmosphere is an important source of contamination of the lakes by Pb (56.3% of total inputs) and Zn (34.8%), but not Cu (8.3%). The mean retention coefficient in five of the lakes is 0.70 (RSD = 29%), 0.72 (24%), and 0.24 (133%) for Pb, Zn, and Cu, respectively; mean total residence time is 0.21 (RSD = 64%), 0.36 (61%), and 0.77 (97%) yr; and mean sedimentation residence time 0.34 (RSD = 73%), 0.91 (99%), and 0.05 (95%) yr. The goodness of fit of the two models are similar, with root mean square error of prediction of +/-0.14, 1.9, and 1.6 mug L-1 for Pb, Zn, and Cu, respectively. The magnitude of the errors in relation to the ranges of concentration suggests that the models for Pb and Zn can be used as fate models for these metals in lake water.

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